|
|
NADP+ + cis-1,2-dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate <=> CO2 + NADPH + 4-methylcatechol
|
1.3.1.67
cis-1,2-dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate dehydrogenase
|
–
|
K
|
|
BRENDA:
BR29445
KEGG:
R05293
MetaCyc:
1.3.1.67-RXN
|
|
|
|
NAD+ + cis-1,2-dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate <=> CO2 + NADH + 4-methylcatechol
|
1.3.1.67
cis-1,2-dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate dehydrogenase
|
–
|
K
|
|
BRENDA:
BR29445-a
KEGG:
R05292
MetaCyc:
1.3.1.67-RXN_WOP
|
|
|
|
5-Methylsalicylate + O2 + NADH + H+ <=> 4-methylcatechol + CO2 + H2O + NAD+
|
1.14.13.1
salicylate 1-monooxygenase
|
–
|
M
|
|
BRENDA:
BS257949
MetaCyc:
RXN-10079
|
|
|
|
4-methylcatechol + O2 <=> 3-methyl-cis,cis-muconate + H+
|
1.13.11.1
catechol 1,2-dioxygenase
1.13.11.3
protocatechuate 3,4-dioxygenase
|
–
–
|
MK
|
|
BRENDA:
BS260576
KEGG:
R05299
MetaCyc:
RXN-10080
SABIO-RK:
4908
|
|
|
|
3,4-Dihydroxyphenylacetate + H+ <=> 4-methylcatechol + CO2
|
4.1.1.83
4-hydroxyphenylacetate decarboxylase
|
–
|
|
|
BRENDA:
BS375437
MetaCyc:
RXN-20409
SABIO-RK:
12325
|
|
|
|
H+ + p-Cresol + NADH + O2 <=> 4-methylcatechol + NAD+ + H2O
|
1.14.12.12
naphthalene 1,2-dioxygenase
1.14.13.236
toluene 4-monooxygenase
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
–
–
|
M
|
|
BRENDA:
BS375901
MetaCyc:
M-CRESOL-METHYLCATECHOL-RXN
|
|
|
|
4-methylsalicylate + O2 + NADH + H+ <=> 4-methylcatechol + CO2 + H2O + NAD+
|
1.14.13.1
salicylate 1-monooxygenase
|
–
|
BMK
|
|
BRENDA:
BS375902
KEGG:
R06939
MetaCyc:
RXN-10078
|
|
|
|
4-methylcatechol + O2 <=> 2-hydroxy-5-methyl-6-oxohexa-2,4-dienoate + H+
|
1.13.11.2
catechol 2,3-dioxygenase
|
–
|
M
|
|
BRENDA:
BS422609
MetaCyc:
RXN-11219
|
|
|
|
3-nitrotoluene + O2 + NADH <=> 4-methylcatechol + nitrite + NAD+
|
1.14.12.23
nitroarene dioxygenase
1.14.12.24
2,4-dinitrotoluene dioxygenase
|
–
–
|
|
|
BRENDA:
BS433262
MetaCyc:
RXN-8814
|
|
|
|
4-nitrotoluene + O2 + NADH <=> 4-methylcatechol + nitrite + NAD+
|
1.14.12.23
nitroarene dioxygenase
1.14.12.24
2,4-dinitrotoluene dioxygenase
|
–
–
|
|
|
BRENDA:
BS433294
MetaCyc:
RXN-16798
|
|
|
|
p-Cresol + NADPH + O2 <=> 4-methylcatechol + NADP+ + H2O
|
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
|
|
|
BRENDA:
BS380182
KEGG:
R03568
|
|
|
|
4-toluenesulfonate + NADH + O2 <=> sulfite + 4-methylcatechol + NAD+
|
1.14.12
1.14.12.14
2-aminobenzenesulfonate 2,3-dioxygenase
|
–
–
|
MK
|
|
KEGG:
R05294
MetaCyc:
TSDOSALCAL-RXN
|
|
|
|
4-methylcatechol + O2 <=> 4-methyl-1,2-benzoquinone
|
1.10.3.1
catechol oxidase
1.14.18.1
tyrosinase
|
–
–
|
|
|
BRENDA:
BS289469
SABIO-RK:
11652
|
|
|
|
p-Cresol + H2O2 <=> 4-methylcatechol + H2O
|
1.11.1.7
peroxidase
1.11.2.6
L-tyrosine peroxygenase
1.14.18.1
tyrosinase
|
–
–
–
|
|
|
BRENDA:
BS455047
SABIO-RK:
6632
|
|
|
|
4-methylcatechol + O2 <=> 2-Hydroxy-5-methyl-cis,cis-muconic_semialdehyde
|
1.13.11.2
catechol 2,3-dioxygenase
|
–
|
K
|
|
KEGG:
R05295
|
|
|
|
4-methylcatechol + O2 <=> 3-methylhexa-2,4-dienedioate
|
1.13.11.1
catechol 1,2-dioxygenase
|
–
|
|
|
BRENDA:
BS417861
|
|
|
|
4-methylcatechol + O2 <=> p-Cresol + H2O
|
1.14.18.1
tyrosinase
|
–
|
|
|
BRENDA:
BS451376
|
|
|
|
p-Cresol + FADH2 + O2 <=> 4-methylcatechol + FAD + H2O
|
1.14.14.20
phenol 2-monooxygenase (FADH2)
|
–
|
|
|
BRENDA:
BS434563
|
|
|
|
p-Cresol + O2 + reduced_acceptor <=> 4-methylcatechol + H2O + A
|
1.14.18.1
tyrosinase
|
–
|
|
|
BRENDA:
BS398029
|
|
|
|
N6-(2-isopentenyl)adenine + 4-methylcatechol + H2O <=> adenine + 3-methylbut-2-enal + reduced_4-methylcatechol
|
1.5.99.12
cytokinin dehydrogenase
|
–
|
|
|
BRENDA:
BS373980
|
|
|
|
N6-isopentenyladenosine + 4-methylcatechol + H2O <=> adenosine + 3-methylbut-2-enal + reduced_4-methylcatechol
|
1.5.99.12
cytokinin dehydrogenase
|
–
|
|
|
BRENDA:
BS373986
|
|
|
|
p-Cresol + O2 <=> 4-methylcatechol + H2O
|
1.14.18.1
tyrosinase
|
–
|
|
|
BRENDA:
BS353341
|
|
|
|
4-methylcatechol + O2 <=> 2-hydroxy-3-methylmuconic_acid_semialdehyde
|
1.13.11.36
chloridazon-catechol dioxygenase
|
–
|
|
|
BRENDA:
BS288896
|
|
|
|
4-methylcatechol + O2 <=> 6-hydroxy-4-methylcyclohexa-2,4-dienone + H2O
|
1.10.3.2
laccase
|
–
|
|
|
BRENDA:
BS261089
|
|
|
|
S-adenosyl-L-methionine + 4-methylcatechol <=> S-adenosyl-L-homocysteine + 2-Methoxy-4-methylphenol
|
2.1.1.68
caffeate O-methyltransferase
|
–
|
|
|
BRENDA:
BS319836
|
|
|
|
4-methylcatechol + ascorbate + O2 <=> 4-methyl-1,2-benzoquinone + dehydroascorbate + H2O
|
1.14.17.B1
|
–
|
|
|
BRENDA:
BS415472
|
|
|
|
3-nitrotoluene + NADH + O2 <=> 3-methylcatechol + 4-methylcatechol + nitrite + NAD+
|
1.14.12.23
nitroarene dioxygenase
|
–
|
|
|
BRENDA:
BS433260
|
|
|
|
2-nitrotoluene + NADH + O2 <=> 4-methylcatechol + nitrite + NAD+
|
1.14.12.23
nitroarene dioxygenase
|
–
|
|
|
BRENDA:
BS433218
|
|
|
|
cis-p-toluate_diol + NAD+ <=> 4-methylcatechol + NADH + H+ + CO2
|
1.3.1.67
cis-1,2-dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate dehydrogenase
|
–
|
|
|
BRENDA:
BS370004
|
|
|
|
m-cresol + NADH + O2 <=> methylhydroquinone + 3-methylcatechol + 4-methylcatechol + NAD+
|
1.14.12.12
naphthalene 1,2-dioxygenase
|
–
|
|
|
BRENDA:
BS389118
|
|
|
|
4-Chlorophenol + NADH + H+ + O2 <=> 4-methylcatechol + NAD+ + H2O
|
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
|
|
|
BRENDA:
BS375872
|
|
|
|
m-cresol + NADH + H+ + O2 <=> 4-methylcatechol + NAD+ + H2O
|
1.14.13.236
toluene 4-monooxygenase
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
–
|
|
|
BRENDA:
BS377122
|
|
|
|
4-Methyl-2-nitrophenol + NADPH + H+ + O2 <=> 4-methylcatechol + NADP+ + H2O + nitrite
|
1.14.13.31
2-nitrophenol 2-monooxygenase
|
–
|
|
|
BRENDA:
BS395883
|
|
|
|
m-cresol + NADPH + O2 <=> 3-methylcatechol + 4-methylcatechol + NADP+ + H2O
|
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
|
|
|
BRENDA:
BS387348
|
|
|
|
2 o-Cresol + NADPH + O2 <=> 3-methylcatechol + 4-methylcatechol + NADP+ + H2O
|
1.14.13.7
phenol 2-monooxygenase (NADPH)
|
–
|
|
|
BRENDA:
BS387123
|
|
|
|
4-Methyl-2-nitrophenol + NADPH + O2 <=> 4-methylcatechol + NADP+ + H2O
|
1.14.13.31
2-nitrophenol 2-monooxygenase
|
–
|
|
|
BRENDA:
BS288366
|
|
|
|
5-methyl-2-nitrophenol + NADPH + O2 <=> 4-methylcatechol + NADP+ + H2O
|
1.14.13.31
2-nitrophenol 2-monooxygenase
|
–
|
|
|
BRENDA:
BS288367
|
|
|
|
4-methylcatechol + O2 <=> 2,3,5-trimethyl-cis-cis-muconate
|
1.13.11.1
catechol 1,2-dioxygenase
|
–
|
|
|
BRENDA:
BS260592
|
|
|
|
4-methylcatechol + O2 <=> 2-hydroxy-3-methyl-6-oxohexa-2,4-dienoate
|
1.13.11.2
catechol 2,3-dioxygenase
1.13.11.39
biphenyl-2,3-diol 1,2-dioxygenase
|
–
–
|
|
|
BRENDA:
BS288881
|
|
|
|
4-methylcatechol + acceptor + H2O <=> 3,4-Dihydroxybenzaldehyde + reduced_acceptor
|
1.17.9.1
4-methylphenol dehydrogenase (hydroxylating)
|
–
|
|
|
BRENDA:
BS287767
|
|